Magnesium
from Magnesium Chloride
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  • Magnesium metal is produced by electrolysis of a molten magnesium chloride electrolyte containing fluoride ions, the electrolyte being derived from holding pond brines which are partially deboronated, concentrated, gelled and spray dried in the presence of hydrochloric acid gas to form discrete particles of high density anhydrous magnesium chloride feed material for electrolytic cells - according to a patented process
  • Accoring to another patented process for producing magnesium metal from dihydrate magnesium chloride comprising the steps of dehydrating MgCI2.2H2O with anhydrous hydrochloric acid (HCI) to obtain anhydrous magnesium chloride in an inert environment, releasing the mixture of hydrous HCI and protection gas; and electrolyzing the anhydrous magnesium chloride in an electrolytic cell fed with hydrogen gas under free oxygen atmosphere content, wherein magnesium metal and anhydrous hydrogen chloride are produced, wherein a part of the hydrous HCI is passed through a scrubbing unit to obtain a hydrochloric acid solution, the other part of the hydrochloric chloride gas is dehydrated by contact with a desiccant agent in a drying unit to produce anhydrous HCI, and wherein the anhydrous HCI produced by at least one of the electrolytic cell and the drying unit is reused to dehydrate the of MgCI2.2H2O.
  • In the electrolytic production of magnesium from an electrolyte comprising magnesium chloride and impurity quantities of magnesium oxide which adversely affects the efficiency of cell operation, the magnesium oxide is chemically and electrolytically removed from the electrolyte by sparging the electrolyte with hydrogen and/or hydrocarbon gas adjacent the anode such that MgO reacts with H2 or, e.g., CH4 and Cl2 (generated at the anode) under the electrical potential of the cell to form magnesium chloride. Similarly, magnesium oxide may be mixed and stirred in molten magnesium chloride and reacted with Cl2 and H2 (and/or hydrocarbon) to form anhydrous MgCl2 for use in magnesium production.
  • Magnesium can be produced either from a pyro-metallurgical process (thermal magnesium oxide reduction) or by electrolysis from magnesium chloride containing molten salt. The latter is the dominant process with about 75% of the total production.
    There are five thermal reduction processes and eight electrolytic process that have been sued in the past or being used at present
Basics
  • Magnesium Technology

Companies

  • Companies in the field

Technology Information

  • Integrating the Production of Freshwater, Salt,
    Magnesium, and Bromine
  • Seawater Bittern a Precursor for Magnesium Chloride Separation
  • Extraction of Valuable Materials from Reverse Osmosis Concentrate
  • Sustainable management of treatment of Desalination plant concentrate
  • The Production Process
  • Magnesium Recovery from Desalination Brine
  • Production of magnesium from desalination
    brine

Consultants

  • Consultant - water treatment solutions
  • Technology Consultancy
  • Technical Consultant

Patents Information

  • Production of Magnesium Metal
  • Process for producing Magnesium Metal from Magnesium Chloride Brines
  • Purification of Magnesium Chloride Cell bath material useful for the production of magnesium metal by Electrolysis
  • System & Process for production of Magnesium Metal & Magnesium hydride from Magnesium containing salts & brines
  • Recovery of Magnesium Chloride from Brines
  • Process for producing Magnesium by Metal dehydrating dihydrate Magnesium Chloride
  • Production of Magnesium Metal
  • Improving the Electrolytic Process for
    Magnesium Production
  • Thermal decomposition of Magnesium Chloride

Project Information

  • Techno-Economic Feasibility of Extracting
    Minerals from Desalination Brines
  • Integrated processes for desalination and
    salt production
  • Magnesium recovery from exhausted brine - Pilot Plant
  • Magnesium: Alternative production routes
  • Supplier - Magnesium Chloride
  • Consultant - Feasibility Reports
  • Consultant - Salt projects

Ordering Information

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