- In addition to new derivatives from the
PBZX family and novel rigid-rod polymers such as rigid-rod
polyimides and aromatic poly(pyridinium salt), there are
several special groups of rigid-rod polymers that have been studied
and developed rapidly after the 1980s.
- Among them are polyphenylenes,
poly(phenylene ethynylene), poly(p-phenylenevinylene) (qv),
polythiophenes, polyanilines, polyquinolines, and some
organometallic polymers .
- The rigid-rod fibers, especially
poly((benzo {1,2-d:4,5 -d } bisoxazole-2,6-diyl)-1,4-phenylene) PBZO,
display superior tensile properties ,thermal stability, flame
resistance, barrier properties, and low smoke generation as well as
low moisture sensitivity.
- Other good properties are cutting and
abrasion resistance, chemical, oxidation, and radiation resistance,
as well as a low
dissipation factor .
- Furthermore, the rigid-rod fibers exhibit
potentially useful electrical and nonlinear optical behavior.
- The rigid-rod polymer fibers also have
rather small creep and stress relaxation. Their creep and stress
relaxation rates are extremely
low compared with the conventional nylon and polyester fibers.
- Rodlike polymers have a finite
degree of flexibility in the sp3-hybridized carbons in the polymer
backbone, whereas rigid-rod polymers are entirely sp2-hybridized and
can only be rotated axially since they have no points of flexibility
along the backbone.
- Rigid rod-like polymers form a nematic
phase which is of the tumbling type at small and moderate shear
rates, to become flow-aligning at high shear rates as a result of
nonlinearity.
|
General
- Rigid-rod polymers
- Rigid-rod polymer
hosts (polyacetylene, polythiophene, etc.)
- Unreinforced
Plastics Get Stiffer
- Past and
future of high performance fibers
- Rigid-rod Type
Polymers: poly(n-hexyl isocyanate)
- Nanotubes as
polymers
- High-performance
fibres
- Polymer data
handbook
Consultancy
- Consultancy from
California
- Consultancy from
Canada
- Consultancy from
Texas
- Consultancy from
U.K
Market
- New rigid-rod
polymer jumps to market
- Self
reinforcing thermoplastic is harder, stronger, stiffer without added
fibers
Patent
- Rigid rod polymer
based on pyridobisimidazole
- Rigid-rod polymers
- Adamantane based
three-dimensional rigid-rod polymers
- Two-dimensional
benzobisoxazole rigid-rod polymers
- Water soluble
rigid-rod polymer
- Negative
birefringent rigid rod polymer films
- Rigid-rod graft
polymers and copolymers
- Compositions
comprising rigid-rod polymers and carbon nanotubes and process for
making the same
- Dihydroxy-pendant
rigid-rod benzobisazole polymer
- Conductive
composites derived from poyaniline and aromatic benzazole rigid-rod
polymers
|
Report
- Compressive
strength in rigid rod polymers
- Steady state and
ultrafast fluorescence depolarisation in rigid rod conjugated
polymers
- The potential of a
new rigid-rod polymer fibre (‘M5’) in advanced composite structures
- Novel synthetic
methods of condensation polymers
and their applications as new composite and optoelectronic
materials
- Molecular/Nano
Level Approaches for the Enhancement of Axial Compressive Properties
of Rigid-Rod Polymers
- Long term creep and
stress rupture of aramid fibre
- Fillers & Additives
- Exciton Migration
in Rigid-Rod Conjugated Polymers
- Molecular
design of rigid-rod polyelectrolytes
Study
- Turbulent Pipe Flow
of "Rod-Like" Polymer Solutions
- Solvent cast
thermoplastic and thermoset rigid-rod molecular composites
- Rigid rod polymer
fillers in acrylic denture and dental adhesive resin systems
- Nonlinear Optical
Properties of Rigid-Rod Polymers
- Nanoscale
Fibrils and Grids: Aggregated Structures from Rigid-Rod Conjugated
Polymers
- Molecular
Conformations
- Mechanical and
fracture behaviour of rigid-rod self reinforced polymers
- Luminescence of
Monolayer Thin Films of the Fully Conjugated Rigid-Rod Polymer
Poly(p-phenylene benzobisthiazole)
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