Phosgene
Introduction, Products,
Patents, Process, Study, Company Profiles, Reports
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- Phosgene is the
chemical compound with the formula COCl2. This colorless gas gained
infamy as a chemical weapon during World War I. It is also a valued
industrial reagent and building block in synthesis of
pharmaceuticals and other organic compounds. In low concentrations,
its odor resembles freshly cut hay or grass.
- Phosgene was first
produced by John Davy (inventor of the ‘Davy Lamp’) at the start of
the 19 th century. The chemical was named by combining the Greek
words ‘phos’ (meaning light) and genesis (birth), as Davy used
sunlight to produce the chemical from carbon monoxide and chlorine.
- Phosgene is produced
by passing purified carbon monoxide and chlorine gas through a bed
of porous activated carbon, which serves as a catalyst.
- Phosgene may also be
produced during testing for leaks of older-style refrigerant gasses.
- The great majority of
phosgene is used in the production of isocyanates, the most
important being toluene diisocyanate (TDI) and methylene diphenyl
diisocyanate (MDI). These isocyanates are precursors to
polyurethanes. Phosgene was used during World War I as a choking
(pulmonary) agent.
- In the research
laboratory phosgene still finds limited use in organic synthesis. A
variety of substitutes have been developed, notably trichloromethyl
chloroformate (“diphosgene”), which is a liquid at room temperature,
and bis(trichloromethyl) carbonate (“triphosgene”), a crystalline
substance.
- Phosgene is an
insidious poison as the odor may not be noticed and symptoms may be
slow to appear. Phosgene can be detected at 0.4 ppm, which is four
times the Threshold Limit Value. Its high toxicity arises from the
action of the phosgene on the proteins in the pulmonary alveoli,
which are the site of gas exchange: their damage disrupts the
blood-air barrier, causing suffocation.
- The primary use of
phosgene is in the production of toluene diisocyanate (TDI), a
precursor of the polyurethane resins used to make foams, elastomers,
and coatings. A rapidly growing use of phosgene is in the
manufacture of polymethylene polyphenylisocyanate (PMPPI), which is
used in the production of rigid polyurethane foams.
- The potential for
phosgene generation by chlorocarbon decomposition exists at
chlorocarbon producing facilities, metallurgical operations,
drycleaning and degreasing facilities, certain types of industrial
fires, and wherever solvents contact heat or ultraviolet light.
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Introduction
- Chemical Information
- The facts on Phosgene
- Phosgene
- Facts About Phosgene
- Chemical Terrorism
Fact Sheet
- Phosgene - Intro
MSDS
- Nonflammable Gas
Mixture
- Phosgene
- Carbonyl Chloride
- Phosgene - Msds
- Carbon
oxychloride
-
Chloroformyl chloride
Products
- Chemlogic
Dosimeter Badges for Phosgene from DOD
- Phosgene
- Triphosgene
Company Profiles
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Company from Delhi
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Company from Gujarat
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Company from New Jersey
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Company from New York
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Another Company from New York
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Company from USA
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Company from Tokyo
Guidelines
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Phosgene
-
Public Handout
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Acute Exposure Guideline Levels for Selected
Airborne Chemicals
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Guidelines for Phosgene
Gas Usage in Laboratories
Process
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Manufacturing Process
-
Phosgene Production
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Production and Uses
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Trends in processing and
manufacturing
Patents
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Phosgene process
-
Phosgene manufacture
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Method for hydrolyzing phosgene
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Process for destroying phosgene
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Phosgene removal process
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Method for producing phosgene
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Reports
- Company's Annual
Report
- BAYER further
increases Phosgene Production
- Phosgene Gas
- Chemical leak at China
factory 'poisons workers
- The formation of
Phosgene
- SNPE boosts phosgene
unit
-
Phosgene
Toxicity
- HPA Compendium of
Chemical Hazards
- Phosgene Toxicity
- Public Information
- Exposure to Phosgene
in Pregnancy
- Toxicology review of
Phosgene
Study
- An ab initio study on
the phosgene–water complex
- Gas chromatographic
determination of phosgene and dichloroacetylene in air
- Estimation of LCt50 of
Phosgene in Sheep
- Evaluation of NBC
Canisters against Phosgene a Chemical Warfare Agent
- Global phosgene
observations from the Atmospheric Chemistry Experiment (ACE) mission
- A Novel Cross-Flow
Microreactor for Kinetic Studies of Catalytic Processes
Market and
Applications
- Phosgene Application
- Phosgene Uses
- From Green to
Sustainable Industrial Chemistry
- Chemical Profile :
Phosgene
- Phosgene Industry -
Use
Consultants
- Company from Chennai
- Company from New York
- Another Company from
New York
- Company from
Washington
- Consultancy Services
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