Ferrous Chloride
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• Iron(II) chloride, also known as ferrous chloride, is the chemical compound of formula FeCl2.
• It has a high melting point, paramagnetic solid, usually obtained as an off-white solid.
• FeCl2 crystallizes from water as the greenish tetrahydrate, which is the form that is most commonly encountered in commerce and the laboratory.
• Ferrous chloride is conveniently prepared using a methanol solution of concentrated hydrochloric acid.
• This reaction gives the methanol solvate, which upon heating in a vacuum at about 160 °C gives anhydrous FeCl2.
• FeBr2 and FeI2 can be prepared analogously.
• FeCl2 prepared in this way exhibits convenient solubility in tetrahydrofuran, a common solvent for chemical reactions.
• In one of two classic syntheses of ferrocene, Wilkinson generated FeCl2 by heating FeCl3 with iron powder.
  Ferric chloride decomposes to ferrous chloride at high temperatures.
• By introducing chlorine gas to ferrous chloride, it is possible to regenerate ferric chloride.
• Pollution Prevention team need to determine how much chlorine gas is required to convert the  ferrous into ferric chloride.
• Ferrous chloride is to find another cleaning agent for the manufactured products.
• Ferrous chloride has a variety of niche applications, but the related compounds ferrous sulfate and ferric chloride enjoy more applications.
• Aside from use in the laboratory synthesis of iron complexes, ferrous chloride serves as a reducing flocculating agent in wastewater treatment,
  especially for wastes containing chromate.
• It is the precursor to hydrated iron(III) oxides that are magnetic pigments.
• Ferrous chloride employed as a reducing agent in organic synthesis.

Introduction

• Ferrous Chloride

Process

• Analysis of iron(II)/iron(III) phytosiderophore complexes by nano-electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry
• Effects of Ferrous Chloride and Iron-Dextran on Lipid Peroxidation In Vivo in Vitamin E and Selenium Adequate and Deficient Rats1
• Extraction of zinc(II), iron (III) & Iron (II) with Binary Mixtures containing tributyl phosphate & diethylhexyl phosphoric acid or cyanex
• Iron(ii)-mediated fragmentation of unsaturated hydroperoxy acetals: a rapid synthetic route to 13-membered macrolides
• Polymerization of methyl methacrylate in the presence of iron(II) complex with tetradentate nitrogen ligands under conditions of atom transfer radical polymerization
• Synthesis and Sublimation Kinetics of a Highly Volatile Asymmetric Iron(II) Amidinate

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