Titanium-Oxychloride                                
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Project at a Glance Contents on the CD ROM
  • Titanium oxychloride is formed in a reaction between titanium chloride (TiCl4) and water.
  • The mixture of tartaric acid and TiOCl2 solution forms a gel on heating on a water bath which decomposes at higher temperatures, > 423 K.
  • Mesoporous titania with an average pore diameter of 2.6 nm and pure rutile crystalline structural wall were prepared by hydrolysis of TiOCl2 aqueous solution at lower temperature by using octyl phenol polyethylene oxide as template-directing agent.
  • Yellow cakes of TiO(OH)2 were dissolved with added HCl solution to form a TiOCl2 solution.
  • The concentration of titanium in the as- preparedTiOCl2 solutionwas 5.27M, and this was used as a stock solution for synthesis of TiO2.
  • The precipitation from the aqueous TiOCl2 solution
    was not by the change of solubility but crystallization, in which crystalline TiO2 precipitates have been already formed at the stage of precipitation.
  • Samples of titanium oxychloride solution stabilized in an acidic medium solution and N,N-dimethylformamide (DMF) were prepared in
    concentration of titanium between 0.05 and 0.7 mol/L-1 at room temperature, denoted TiDMF sol. When mixing the titanium oxychloride and dimethylformamide solutions a double hydrolysis reaction takes place: DMF reacts with HCl to form dimethyl ammonium chloride and methanoic acid. At the same time, the consumption of HCl enables agentle control over the inorganic polymerization.
  • TiOCl2 acid solution hydrolyses N,N-dimethylformamide leading to the formation of dimethylammonium chloride and methanoic acid.
  • The inorganic polymerisation is gently controlled by the slow consumption of hydrochloric acid, and this one-pot process enables the preparation of novel titanium oxide-based nanoparticles in sols or gels.
  • TiOCl2 acid solution hydrolyzes N,N-dimethylformamide (DMF) at room temperature, leading to the formation of dimethylammonium chloride (DMACl) and methanoic acid.

Process

  • Effects of Negative Ions in Aqueous Ti Solution on Formation of Ultrafine TiO2 Powder by Low Temperature Homogeneous Precipitation
  • First-principles thermochemistry for the
    production of TiO2 from TiCl4
  • Mesoporous titania–silica composite from sodium silicate and titanium oxychloride. Part II: one-pot co-condensation method
  • Photocatalytic Characteristics of Nanometer-Sized Titania Powders Fabricated by a Homogeneous-Precipitation Process

Synthesis

  • Modelling the Chloride Process for Titanium Dioxide Synthesis
  • Photosensitive Titanium Oxo-polymers: Synthesis and Structural Characterization
  • Synthesis of rutile Tio2 with high specific surface area by self hydrolysis of Tiocl2 in the presence of SDS

Application

  • Estimation of reaction conditions for synthesis
    of nanosized brookite-type titanium dioxide from aqueous TiOCl2 solution
  • Improving the environmental performance of manufacturing systems via exergy, techno-ecological synergy, and optimization
  • Life cycle inventory study of biologically inspired self-cleaning surfaces
  • Tio2 Post treatment

MSDS & Product

  • Oxychloride 6102
  • Titanium Oxychloride Aqueous Solution
  • Kronos® 6020
  • Titanium Oxychloride

Suppliers

  • Titanium Oxychloride Suppliers
  • Titanium Oxychloride China Suppliers
  • Titanium Oxychloride Manufacturer & Suppliers
  • Titanium Oxychloride Exporters
Company Profile & Consultant
  • Company Worldwide
  • Global company
  • Consultant from China
  • Consultant from Michigan
  • Consultant from USA
  • Global Consultant

Toxicity & Report

  • The characterization and photocatalytic properties of mesoporous rutile TiO2 powder synthesized through self-assembly of nano crystals
  • Titanium Tetrachloride Toxicology Profile
  • Abnormalities of pulmonary function and pleural disease among titanium metal production workers.

Patent

  • Preparation of pure titanium dioxide with anatase crystal structure from titanium oxychloride solution
  • Method for production of mono-dispersed and crystalline TiO2 ultrafine powders for aqueous TiOCl2 solution using homogeneous precipitation
  • Method for applying an inorganic titanium coating to a glass surface
  • Process for controlling the passivation of aluminum chloride formed in the
    chlorination of titanium-containing ores
  • Process to make rutile pigment from aqueous titanium solutions

Technology

  • The characterization and photocatalytic properties of mesoporous rutile TiO2 powder synthesized through self-assembly of nano crystals
  • Synthesis of nanocrystalline TiO2 by tartarate gel method
  • Monodispersed titanium oxide particles with nanometer scale and narrow size distribution in nonaqueous media
  • OxTi-Photobatterie

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