- Classified as an alkene, ethene (or
ethylene).
- Ethylene is the chemical compound
with the formula C2H4. It is the simplest alkene. Because it contains a
double bond, ethylene is called an unsaturated hydrocarbon or an olefin.
- This hydrocarbon has four hydrogen
atoms bound to a pair of carbon atoms that are connected by a double
bond. All six atoms that comprise ethylene are coplanar. The H-C-H angle
is 117°, close to the 120° for ideal sp˛ hybridized carbon.
- Alkenes are also refered to as
"olefins" due to their oil-forming characteristics. The location of the
double bond determines the reactivity site, or functional group
property.
- Ethylene is produced in the
petrochemical industry by steam cracking.
- In this process, gaseous or light
liquid hydrocarbons are heated to 750–950 °C, inducing numerous free
radical reactions followed by immediate quench to freeze the reactions.
This process converts large hydrocarbons into smaller ones and
introduces unsaturation. Ethylene is separated from the resulting
complex mixture by repeated compression and distillation.
- Ethylene can be conveniently produced
in the laboratory by distilling absolute ethanol with an excess of
concentrated sulfuric acid and washing the distillate vapor stream in an
aqueous solution of sodium hydroxide to remove the sulfur dioxide
contaminant.
- Small quantities of dilute ethylene
can be obtained from refinery streams. In South Africa, ethylene is
produced by the Fisher-Tropsch process from gases obtained by coal
gasification.
- Efforts have been made to develop
processes which can crack crude or residual oil but they suffer from
high operating costs.
- Ethylene may also be produced from
ethanol in fixed or fluid-bed reaction systems.
- Ethylene is a naturally produced gas
that is the ripening trigger for most fruit, vegetables, flowers and
ornamentals. It is therefore an
important factor to be considered in
the management strategy when storing these products.
- Ethylene plays a role in the
postharvest life of many horticultural crops.
- The application of ethylene at a
controlled rate means that the products can be presented to the customer
as “ready to eat”.
- Ethylene is used as a raw material in
the production of plastics, fibers and other organic chemicals that are
ultimately consumed in the packaging, transportation and construction
industries and in a multitude of industrial and consumer markets.
- Ethylene is an extremely important
building block in the petrochemical industry. It can undergo many types
of reactions which leads to a plethora of major chemical products. A
list of some major types of reactions includes,Polymerization,
Oxidation, Halogenation and Hydrohalogenation, Alkylation, Hydration,
Oligomerization, Oxo-reaction, and a ripening agent for fruits and
vegetables.
- The global ethylene production
amounted to about 110 million metric tons, with an estimated value of
$122 billion.
- Global demand for ethylene is
forecast to grow 4.6% per year during 2006-2011, and then slow to 3.4%
from 2011 through 2016. The largest world market for ethylene is the
production of polymers, principally polyethylenes. During 2006–2011,
polyethylenes will continue to be the largest consumer of ethylene and
are expected to grow by 4.2% per year.
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General
- General information about
ethylene
- About ethylene
- Nature of ethylene
- Description of ethylene
Process
- Methane to Ethylene - BHP
Process
- Production of ethylene glycol
- Ethylene Oxide Process
Monitoring
- Process for Maximum Ethylene
Production
- Ethylene Production and Manufacturing
Process
- Ethylene processing
Functions and
Properties
-
Ethylene Propylene
Rubbers – Properties and Applications of Ethylene Propylene Diene (EPDM)
and Ethylene Propylene Copolymers (EPM)
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Ethylene glycol-mechanism of action
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Mechanical Properties of LDPE/Ethylene-1-butene Copolymer
Films Crosslinked by Radiation
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Properties of ethylene
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Ethylene as a modulator of disease resistance in plants
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Ethylene functions in the moss, Physcomitrella patens
Company Profiles
- Company from India
- Company from Korea
- Company from Germany
- Company from Saudi Arabia
Plant
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Plant from Pennsylvania
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Plant from China
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Plant from USA
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Plant from Deutschland
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Plant from United Kingdom
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Plant from Paris
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Plant from Thailand
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Plant from Scotland
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Plant from Sweden
Patent
- Homopolymer of ethylene
- Polymerization of ethylene
- Process for the production of
ethylene
- Process for co-polymerization of
propylene and ethylene
- Process for production of
ethylbenzene from dilute ethylene streams
- Thermosetting ethylene/alpha-olefin
composition and safety glass interlayer film made from the
composition
- Use of ethylene for increasing crop
yields
Consultants and
projects
- Consultant from Wilmington, DE
- Consultant from Minnesota
- Consultant from India
- Alloys for ethylene production
- Ethylene reconstruction and
extension
- Simultaneous production of ethylene
and synthesis gas
Technology
- China starts producing ethylene out
of corn
- Economic analysis of a new gas to
ethylene technology
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Protocol for the verification of ethylene oxide treatment
technology
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Ethylene technology from Lummus Technology
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Ethylene technology from ABB
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New Technologies for Working with Ethylene
Product
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Ethylene dibromide
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Ethylene glycol
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Ethylene pure gas
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Ethylene scrubber
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Application
- Ethylene glycols
- Non-Supported Applications of MEGlobal Ethylene Glycol Products
- Synthesis of novel poly (ethylene glycol) based polyurethanes for
drug delivery systems
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Postharvest Ethylene: A critical factor in quality
management
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Ethylene in cold stores
Production
- Ethylene Production by Botrytis cinerea
- Material balances Ethylene Oxide Production
- Ethylene Oxide Production
- Ethylene production
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Ethylene Production and Respiration Rate in 'Green Gage'
Plums
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Generation and ethylene production of transgenic
carnations harboring ACC synthase cDNA in sense or antisense orientation
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Ethylene production and storage potential in 'cacanska
najbolja' plums
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Production of ethylene and cyclohexane in a catalytic
membrane reactor
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Production of ethylene
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Stress-induced ethylene production in flower parts of cut
carnation flowers cv. light pink tasman
Material safety data
sheet
- Material safety data sheet for ethylene
- Ethylene dichloride safety data sheet
- Safety data for 1,4-dioxane
- Safety data for ethylene
- Ethylene safety data sheet
- Ethylene fact sheet
- Safety data for ethylene glycol
- Safety data for poly(ethylene glycol) tetrahydrofurfuryl ether
- Material safety data sheet of ethylene vinyl acetate emulsion
Market
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South East Asia - Cashing in on Ethylene
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Ethylene global demand
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Petrochemicals firms take a stand against oil price
volatility
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Ethylene Competitiveness: A new global multi-client
service
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Ethylene market outlook
Report
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Breakthrough may revolutionize ethylene production
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Ethylene product description
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Argonne breakthrough may revolutionize ethylene production
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Sinopec launches million-ton ethylene project in N. China
Suppliers and
Buyer
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Suppliers of ethylene
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Suppliers and manufacturers of ethylene
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Ethylene suppliers
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Importer of ethylene
Safety and
Risk
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Ethylene Oxide Health And Safety Update
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Ethylene product risk profile
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Guidance note for the safe use of ethylene oxide in
sterilisation/fumigation processes
Grades
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Ethylene glycol-industrial grade
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Polymer grade ethylene measurement
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Polyethylene glycol
Guides
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Guidelines for the distribution of ethylene oxide
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Ethylene oxide fact sheet
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Ethylene product stewardship guidance manual
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